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type="text/css"></style> <div id="ct" class="ct2 wp cl"> <div class="mn"> <div class="bm_haa cl"> <div class="bm_h cl"> <a href="http://www.oecr.com/portal.php?mod=rss&catid=57" class="y xi2 rss" target="_blank" title="RSS">订阅</a><h1 class="xs2">文章</h1> </div></div> <div class="kjkjb"> <div class="bm vw" style="margin-bottom:0;"> <div class="h hm"> <div class="zxtoux"><img src="http://www.oecr.com/uc_server/avatar.php?uid=54876&size=small" /></div> <h1 class="ph">大阪大学研制新型纸质电致变色显示装置 </h1> <p class="xg1"> 时间：2018-5-9 09:47<a class="zz" href="home.php?mod=space&uid=54876">作者：update</a> 阅读<em id="_viewnum">(753)</em> 评论: <a href="http://www.oecr.com/portal.php?mod=comment&id=6605&idtype=aid" title="查看全部评论"><em id="_commentnum">5</em></a></p> <div class="zxfb" ><a href="http://www.oecr.com/portal.php?mod=rss&catid=57" class="y xi2 rss" target="_blank" title="RSS">订阅</a></div> </div> <!--[diy=diysummarytop]--><div id="diysummarytop" class="area"></div><!--[/diy]--> <div class="s"> <div class="ss"><div><span>导读： </span>大阪大学的一支研究团队，刚刚结合了一种“高透明纸”（纳米纤维素材质，可见光透射率 90%）和一种由纤维素纸浆支撑的传统“白纸”—— 从而打造出了高透明度的电极和高能见度的白色电解液、并且生产出了基于纸张的 ...</div> </div> <!--[diy=diysummarybottom]--><div id="diysummarybottom" class="area"></div><!--[/diy]--> <div class="d"> <!--[diy=diycontenttop]--><div id="diycontenttop" class="area"></div><!--[/diy]--> <table cellpadding="0" cellspacing="0" class="vwtb"><tr><td id="article_content"><div> 大阪大学的一支研究团队，刚刚结合了一种“高透明纸”（<a href="http://material.oecr.com" target="_blank" class="relatedlink">纳米</a>纤维素材质，可见光透射率 90%）和一种由纤维素纸浆支撑的传统“白纸”—— 从而打造出了高透明度的电极和高能见度的白色电解液、并且生产出了基于纸张的电致变色（EC）<a href="http://display.oecr.com" target="_blank" class="relatedlink">显示</a>屏。电致变色装置的原理是，当在 EC 电极上施加电压时，离子或<a href="http://electronic.oecr.com" target="_blank" class="relatedlink">电子</a>会进入电解液中的 EC 层（离子溶液），从而表现出染色或脱色的特性。</div><div><br></div><div><p style="text-align: center;"><a href="data/attachment/portal/201805/09/094605i4fflpdp8sz2pyl0.png" target="_blank"><img src="data/attachment/portal/201805/09/094605i4fflpdp8sz2pyl0.png"></a></p></div><div><br></div><div style="text-align: center;"> （研究配图 1：大阪大学研制出新型“纸张”电解质）</div><div><br></div><div> 传统电池变色装置的已知问题是 ——（1）为了防止电解质的泄露，就必须做好密封，但<a href="http://opticalfilm.oecr.com" target="_blank" class="relatedlink">薄膜</a>的制作很是困难；（2）随着电解液的蒸发，EC 的性能也会有所衰减。</div><div><br></div><div> 好消息是，由 Hirotaka Koga 带领的研究团队，已经通过氢键，成功地纸张纤维素的表面上，打造出了一种支持非易失性电解液的新型纸质电解质。</div><div><br></div><div> 其名叫 1-丁基-3-甲基咪唑-4-氟硼酸根 离子液体化合物（BF4），此外在由纳米纤维素制成的透明纸的整个表面上，均匀地涂覆了带有电致变色功能的导电聚合物（PEDOT:PSS）。</div><div><br></div><div><p style="text-align: center;"><a href="data/attachment/portal/201805/09/094637dxhrehqqrklkqllx.png" target="_blank"><img src="data/attachment/portal/201805/09/094637dxhrehqqrklkqllx.png"></a></p></div><div><br></div><div style="text-align: center;"> （研究配图 2：传统电致变色显示屏与新型纸质 EC 方案的对比）</div><div><br></div><div> 通过一种类似三明治的夹层结构，研究团队开发出了一种 EC 纸装置。这种电致变色方案不仅解决了之前提到的那些问题，同时拥有纸张的柔韧、易弯曲特性。</div><div><br></div><div> 此外，一种具有高光学发射系数的白色纸电解质，也提高了 EC 显示屏的可见性。研究团队称之可兼顾传统的书写介质、以及电致显示特性。</div><div><br></div><div><p style="text-align: center;"><a href="data/attachment/portal/201805/09/094647mzikqavz33pkgya8.gif" target="_blank"><img src="data/attachment/portal/201805/09/094647mzikqavz33pkgya8.gif"></a></p></div><div style="text-align: center;"> （研究配图 3：功能分子在高性能复合<a href="http://material.oecr.com" target="_blank" class="relatedlink">材料</a>的开发中发挥了重要的作用）</div><div><br></div><div> 结合成功开发的其它基于纸质的电子器件，比如内存、<a href="http://material.oecr.com" target="_blank" class="relatedlink">晶体</a>管、天线、以及超级电容，我们就可以制造出新型的“纸质电子图书”。</div><div><br></div><div> 有关这项研究的详情，已经发表在近日出版的美国化学学会《应用材料与界面》（ACS Applied Materials and Interfaces）期刊上，原标题为：</div><div><br></div><div> 《Ionic Liquid Mediated Dispersion and Support of Functional Molecules on Cellulose Fibers for Stimuli-Responsive Chromic Paper Devices》</div><div><br></div><div><p microsoft="" yahei",="" simsun;="" background-color:="" rgb(255,="" 255,="" 255);="" text-align:="" 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