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class="ss"><div><span>导读： </span>红外非线性光学晶体是全固态激光器的核心器件。砷化物虽具有强非线性光学响应和高热导率，但其窄带隙导致的泵浦光吸收问题长期制约其应用，突破带隙限制成为该领域的核心难题。</div> </div> <!--[diy=diysummarybottom]--><div id="diysummarybottom" class="area"></div><!--[/diy]--> <div class="d"> <!--[diy=diycontenttop]--><div id="diycontenttop" class="area"></div><!--[/diy]--> <table cellpadding="0" cellspacing="0" class="vwtb"><tr><td id="article_content"><div class="xl_content" style="margin: 0px; padding: 0px; border: 0px; list-style: none; color: rgb(68, 68, 68); font-family: 微软雅黑; font-size: 16px;"><div class="trs_editor_view TRS_UEDITOR trs_paper_default trs_word trs_web" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;"><p id="paragraph" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;">红外非线性光学<a href="http://material.oecr.com" target="_blank" class="relatedlink">晶体</a>是全固态<a href="http://laser.oecr.com" target="_blank" class="relatedlink">激光</a>器的核心器件。砷化物虽具有强非线性光学响应和高热导率，但其窄带隙导致的泵浦光吸收问题长期制约其应用，突破带隙限制成为该领域的核心难题。</p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;">近期，中国科学院新疆理化技术研究所研究团队在四元砷化物非线性光学<a href="http://material.oecr.com" target="_blank" class="relatedlink">材料</a>研发中取得突破。通过引入大极化率各向异性的As–As同原子键，消除As原子非键<a href="http://electronic.oecr.com" target="_blank" class="relatedlink">电子</a>对，团队在A<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">II</sup>-B<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">III</sup>-C<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">IV</sup>-As体系中成功设计并合成首例经实验验证的四元砷化物材料SrGa<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">3</sub>Si<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">4</sub>As<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">11</sub>。As–As键的引入同时增强了非线性光学响应、带隙和双折射率，材料展现出优异的综合性能。</p><p id="paragraph" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;">研究成果丰富了砷化物结构多样性，确立了“包含同原子键合砷化合物”作为高性能长波红外非线性光学材料的新兴体系。</p><p id="paragraph" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;">相关研究成果发表在《德国应用化学》（<em style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; line-height: 32px !important;">Angewandte Chemie International Edition</em>）上。</p><p id="paperURL" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;"><br></p><p style="text-align: center;"><a href="data/attachment/portal/202605/08/093350cythugt11vn8668c.png" target="_blank"><img src="data/attachment/portal/202605/08/093350cythugt11vn8668c.png"></a></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-align: center; text-indent: 0em; margin-bottom: 26px !important; line-height: 32px !important;">砷化物中远红外非线性光学晶体研究取得进展</p></div></div><div class="xl_bottom" style="margin: 0px; padding: 20px 0px; border-width: 0px 0px 1px; border-top-style: initial; border-right-style: initial; border-bottom-style: dashed; border-left-style: initial; border-top-color: initial; border-right-color: initial; border-bottom-color: rgb(227, 227, 227); border-left-color: initial; border-image: initial; list-style: none; line-height: 28px; overflow: hidden; color: rgb(68, 68, 68); font-family: 微软雅黑;"><p microsoft="" yahei",="" simsun;="" background-color:="" rgb(255,="" 255,="" 255);="" overflow-wrap:="" normal;="" border:="" 0px="" 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