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type="text/css"></style> <div id="ct" class="ct2 wp cl"> <div class="mn"> <div class="bm_haa cl"> <div class="bm_h cl"> <a href="http://www.oecr.com/portal.php?mod=rss&catid=57" class="y xi2 rss" target="_blank" title="RSS">订阅</a><h1 class="xs2">文章</h1> </div></div> <div class="kjkjb"> <div class="bm vw" style="margin-bottom:0;"> <div class="h hm"> <div class="zxtoux"><img src="http://www.oecr.com/uc_server/avatar.php?uid=54876&size=small" /></div> <h1 class="ph">长波红外非线性光学材料研究获进展 </h1> <p class="xg1"> 时间：2025-6-26 07:50<a class="zz" href="home.php?mod=space&uid=54876">作者：update</a> 阅读<em id="_viewnum">(274)</em> 评论: <a href="http://www.oecr.com/portal.php?mod=comment&id=10286&idtype=aid" title="查看全部评论"><em id="_commentnum">5</em></a></p> <div class="zxfb" ><a href="http://www.oecr.com/portal.php?mod=rss&catid=57" class="y xi2 rss" target="_blank" title="RSS">订阅</a></div> </div> <!--[diy=diysummarytop]--><div id="diysummarytop" class="area"></div><!--[/diy]--> <div class="s"> <div class="ss"><div><span>导读： </span>红外非线性光学晶体作为激光频率转换的关键器件，在全固态激光器中具有重要的应用。当前商用的红外非线性光学晶体主要包括黄铜矿型化合物如AgGaS2， AgGaSe2和ZnGeP2 等。然而，由于各自本征的性能缺陷，这些材料已 ...</div> </div> <!--[diy=diysummarybottom]--><div id="diysummarybottom" class="area"></div><!--[/diy]--> <div class="d"> <!--[diy=diycontenttop]--><div id="diycontenttop" class="area"></div><!--[/diy]--> <table cellpadding="0" cellspacing="0" class="vwtb"><tr><td id="article_content"><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;"><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">红外非线性光学<a href="http://material.oecr.com" target="_blank" class="relatedlink">晶体</a>作为<a href="http://laser.oecr.com" target="_blank" class="relatedlink">激光</a>频率转换的关键器件，在全固态激光器中具有重要的应用。当前商用的红外非线性光学晶体主要包括黄铜矿型化合物如</span>AgGaS<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">2</sub><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">， </span>AgGaSe<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">2</sub><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">和</span>ZnGeP<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">2 </sub><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">等。然而，由于各自本征的性能缺陷，这些<a href="http://material.oecr.com" target="_blank" class="relatedlink">材料</a>已不能完全满足当前长波红外激光技术发展的需求，亟需突破现有材料性能的限制，发展高性能新型长波红外非线性光学材料。</span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;"><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">近期，中国科学院新疆理化技术研究所的科研人员通过系统分析现有红外非线性光学材料的性能来源，提出协同组装优势基元构建新型红外非线性光学材料的结构设计思路，并以A<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">Ⅱ</span></sup>B<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">Ⅱ</sup>C<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">Ⅳ</span></sup>Q<sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">Ⅵ<span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;"></span></sup><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">4</span></sub>家族为模板，实现了该家族硒化物带隙及二阶非线性光学效应的有效调控，获得了两例长波红外非线性光学材料</span>Sr<span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">CdSiSe</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">4</span></sub><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">和</span><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">BaCdSiSe</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">4</span></sub><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">。</span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;"><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">这两例化合物具有强的二阶非线性光学响应，</span>是AgGaS<sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;">2</sub>的2.1至2.7倍<span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">，</span><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">且材料的带隙为2.67至2.78 eV，属于宽带隙<a href="http://sensor.oecr.com" target="_blank" class="relatedlink">半导体</a>，激光损伤阈值达到商用</span><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">AgGaS</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">2</span></sub><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">材料的</span>4<span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">倍，有望用于高效、高功率长波红外激光的输出。值得一提的是，</span>Sr<span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">CdSiSe</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">4</span></sub><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">为一同成分熔融化合物</span><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">，具有较好的晶体生长习性，有利于实用化大尺寸单晶的生长。同时，实验及计算的结果表明，</span>Sr<span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">CdSiSe</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">4</span></sub><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">和</span><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">BaCdSiSe</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">4</span></sub><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">化合物中优异的综合性能主要归因于</span><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">[A</span><sup style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">II</span></sup><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">Se</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">8</span></sub><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">]、[CdSe</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">4</span></sub><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">] 和 [SiSe</span><sub style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; font-size: 16px !important; line-height: 32px !important;"><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">4</span></sub><span lang="de-DE" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">]</span><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; margin-bottom: 26px !important; line-height: 32px !important;">优势基元的协同组装。</span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; font-family: 微软雅黑; color: rgb(68, 68, 68); background-color: rgb(255, 255, 255); text-indent: 2em; text-align: justify; margin-bottom: 26px !important; line-height: 32px !important;"><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; margin-bottom: 26px !important; line-height: 32px !important;">相关研究成果发表在</span><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; margin-bottom: 26px !important; line-height: 32px !important;">《先进功能材料》<em style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; line-height: 32px !important;">（</em></span><em style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; text-indent: 2em; margin-bottom: 26px !important; line-height: 32px !important;">Advanced Functional Materials</em><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; margin-bottom: 26px !important; line-height: 32px !important;"><em style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; margin-bottom: 26px !important; line-height: 32px !important;">）</em>上。研究工作得到</span><span style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; margin-bottom: 26px !important; line-height: 32px !important;">中国科学院战略性先导科技专项</span><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; text-indent: 2em; margin-bottom: 26px !important; line-height: 32px !important;">、国家自然科学基金及新疆维吾尔自治区自然科学基金等的支持。</span></p><p style="text-align: center;"><a href="data/attachment/portal/202506/26/075107wjnvnhz2vci2jl1u.gif" target="_blank"><img src="data/attachment/portal/202506/26/075107wjnvnhz2vci2jl1u.gif"></a></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; line-height: 1.5em; font-family: 微软雅黑; color: rgb(68, 68, 68); text-indent: 0em; background-color: rgb(255, 255, 255); text-align: center; margin-bottom: 26px !important;"><span lang="zh-CN" style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; line-height: 1.5em; margin-bottom: 26px !important;">协同组装优势结构基元实现红外非线性光学材料中关键性能的平衡</span></p><p style="margin-top: 0px; margin-right: 0px; margin-left: 0px; padding: 0px; border: 0px; list-style: none; font-size: 16px; line-height: 1.5em; font-family: 微软雅黑; color: rgb(68, 68, 68); text-indent: 0em; background-color: rgb(255, 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<dd>呵呵，低调，低调！</dd> </dl><a name="comment_anchor_35931"></a> <dl id="comment_35931_li" class="ptm pbm bbda cl"> <dt class="mbm"> <span class="y xw0 xi2"> <a href="javascript:;" onclick="portal_comment_requote(35931, '10286');">引用</a> </span> <a href="http://club.oecr.com/space-uid-7230.html" class="xi2 xw1" c="1">skyrambler</a> <span class="xg1 xw0">2025-6-26 08:50</span> </dt> <dd>能在手机上oecr的感觉真的挺好。</dd> </dl><a name="comment_anchor_35930"></a> <dl id="comment_35930_li" class="ptm pbm bbda cl"> <dt class="mbm"> <span class="y xw0 xi2"> <a href="javascript:;" onclick="portal_comment_requote(35930, '10286');">引用</a> </span> <a href="http://club.oecr.com/space-uid-93767.html" class="xi2 xw1" c="1">cszcxh</a> <span class="xg1 xw0">2025-6-26 08:50</span> </dt> <dd>改版后还不错。</dd> </dl><a name="comment_anchor_35929"></a> <dl id="comment_35929_li" class="ptm pbm bbda cl"> <dt class="mbm"> <span class="y xw0 xi2"> <a href="javascript:;" onclick="portal_comment_requote(35929, '10286');">引用</a> 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